Despite the rich coordination chemistry, hydroxylamines are rarely used as ligands for transition metal coordination compounds. Here we designed macrocyclic poly-N-hydroxylamines (crown-hydroxylamines) that form complexes containing a d-metal ion and coordinate by up to six hydroxylamine fragments.
Pakistan is a typical arid region where enhanced rainfall is more likely to cause floods. New research shows that the Middle East warming is increasing Pakistan's exposure to such disasters.
Efficient optical plasmonic tweezer-controlled single-molecule SERS characterization of pH-dependent amylin species in aqueous milieus
Direct time-resolved observation of surface-bound carbon dioxide radical anions on metallic nanocatalysts
A comprehensive understanding of the catalytic CO2 reduction mechanism has been limited by challenging direct time-resolved observation of the elementary steps. Here, we use pulse radiolysis to observe the stabilization processes towards well-defined nanoscale metallic sites.
Unlocking the potential of allogeneic Vδ2 T cells for ovarian cancer therapy through CD16 biomarker selection and CAR/IL-15 engineering
We employed CD16 as a biomarker to identify and select Vδ2 T cell PBMC donors. CD16 high Vδ2 T cells were then engineered with a Mesothelin-targeted chimeric antigen receptor and soluble IL-15 for the treatment of ovarian cancers