Vessel-Controlled Chemodivergence Meets Vinylcyclopropane–Cyclopentene Rearrangement
Our work reveals that the vessel itself dictates product selectivity: switching between glass and plastic enables chemodivergent Rh-catalyzed enantioconvergent rearrangement of vinyl gem-difluorocyclopropanes to cyclopentenones or gem-difluorocyclopentenes.