Core–Shell IrPt Nanoalloy on La/Ni–Co3O4 for High-Performance Bifunctional PEM Electrolysis with Ultralow Noble Metal Loading

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Core–Shell IrPt Nanoalloy on La/Ni–Co3O4 for High-Performance Bifunctional PEM Electrolysis with Ultralow Noble Metal Loading
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Core–Shell IrPt Nanoalloy on La/Ni–Co3O4 for High-Performance Bifunctional PEM Electrolysis with Ultralow Noble Metal Loading - Nano-Micro Letters

The development of highly efficient and durable bifunctional catalysts with minimal precious metal usage is critical for advancing proton exchange membrane water electrolysis (PEMWE). We present an iridium–platinum nanoalloy (IrPt) supported on lanthanum and nickel co-doped cobalt oxide, featuring a core–shell architecture with an amorphous IrPtOx shell and an IrPt core. This catalyst exhibits exceptional bifunctional activity for oxygen and hydrogen evolution reactions in acidic media, achieving 2 A cm−2 at 1.72 V in a PEMWE device with ultralow loadings of 0.075 mgIr cm−2 and 0.075 mgPt cm−2 at anode and cathode, respectively. It demonstrates outstanding durability, sustaining water splitting for over 646 h with a degradation rate of only 5 μV h−1, outperforming state-of-the-art Ir-based catalysts. In situ X-ray absorption spectroscopy and density functional theory simulations reveal that the optimized charge redistribution between Ir and Pt, along with the IrPt core–IrPtOx shell structure, enhances performance. The Ir–O–Pt active sites enable a bi-nuclear mechanism for oxygen evolution reaction and a Volmer–Tafel mechanism for hydrogen evolution reaction, reducing kinetic barriers. Hierarchical porosity, abundant oxygen vacancies, and a high electrochemical surface area further improve electron and mass transfer. This work offers a cost-effective solution for green hydrogen production and advances the design of high-performance bifunctional catalysts for PEMWE. Graphical Abstract

As green hydrogen scales toward gigawatt production, proton-exchange-membrane water electrolysis (PEMWE) is throttled by scarce, high-loading precious-metal catalysts. Now a Shanghai Jiao Tong University-led team (Profs. Fuqiang Huang, Wenjiang Ding & Lina Chong) reports a record-breaking bifunctional catalyst that slashes iridium and platinum use by >70 % while delivering multi-year durability in a real PEMWE cell.

Why Low-PGM Bifunctional Catalysts Matter

  • Cost Bottleneck: State-of-the-art anodes need 2–4 mg cm-2—far above the DOE 2026 target of <0.5 mg cm-2.
  • Performance Gap: Pt is unrivalled for HER but oxidizes to insulating PtO2 under OER conditions; Ir resists corrosion but is HER-poor.
  • Manufacturing Simplification: One catalyst for both electrodes halves coating steps, spare-part inventory and stack cost.

Innovative Design & Features

  • Core–Shell IrPt Nanoalloy (2 nm): Metallic IrPt core guarantees conductivity; amorphous IrPtO shell supplies abundant *OH/*O binding sites.
  • La/Ni-Co3O4 Hierarchical Support: 144 m2 g-1 BET, 5.5 nm mesopores and 30 % oxygen vacancies accelerate water access, gas release and electron transfer.
  • Bi-Nuclear OER Pathway: Adjacent *O on Ir–O–Pt couple directly to O2, skipping high-energy *OOH and avoiding lattice-oxygen loss.
  • Volmer–Tafel HER: 26 mV dec-1 Tafel slope on Ir–O–Pt delivers Pt-like kinetics at 1/8 the Pt loading.

Applications & Future Outlook

  • Real-Cell Validation: Membrane-electrode assemblies with 0.075 mg cm-2 anode + 0.075 mg cm-2 cathode reach 2 A cm-2 at 1.72 V and 72 % electrical efficiency—outperforming commercial 0.2 mg // 0.3 mg benchmarks.
  • 646 h Continuous Operation: Degradation only 5 µV h-1; projected lifetime >34 000 h under DOE protocol.
  • Green-H2 Cost Roadmap: Catalyst cost falls from $25.2 to $7.9 kW-1; next targets are 1 A cm-2 at 1.55 V and roll-to-roll CCM coating for 1 MW stacks.

This work proves that sub-0.1 mg cm-2 PGM loadings can still unlock multi-ampere electrolysis, offering an immediately translatable route to affordable, grid-scale green hydrogen. Stay tuned for pilot-scale stack tests from the Chong–Huang–Ding joint laboratory at SJTU!

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