Directional Three‑Dimensional Macroporous Carbon Foams Decorated with WC1−x Nanoparticles Derived from Salting‑Out Protein Assemblies for Highly Effective Electromagnetic Absorption

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Directional Three‑Dimensional Macroporous Carbon Foams Decorated with WC1−x Nanoparticles Derived from Salting‑Out Protein Assemblies for Highly Effective Electromagnetic Absorption
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Directional Three-Dimensional Macroporous Carbon Foams Decorated with WC1−x Nanoparticles Derived from Salting-Out Protein Assemblies for Highly Effective Electromagnetic Absorption - Nano-Micro Letters

Directional three-dimensional carbon-based foams are emerging as highly attractive candidates for promising electromagnetic wave absorbing materials (EWAMs) thanks to their unique architecture, but their construction usually involves complex procedures and extremely depends on unidirectional freezing technique. Herein, we propose a groundbreaking approach that leverages the assemblies of salting-out protein induced by ammonium metatungstate (AM) as the precursor, and then acquire directional three-dimensional carbon-based foams through simple pyrolysis. The electrostatic interaction between AM and protein ensures well dispersion of WC1−x nanoparticles on carbon frameworks. The content of WC1−x nanoparticles can be rationally regulated by AM dosage, and it also affects the electromagnetic (EM) properties of final carbon-based foams. The optimized foam exhibits exceptional EM absorption performance, achieving a remarkable minimum reflection loss of − 72.0 dB and an effective absorption bandwidth of 6.3 GHz when EM wave propagates parallel to the directional pores. Such performance benefits from the synergistic effects of macroporous architecture and compositional design. Although there is a directional dependence of EM absorption, radar stealth simulation demonstrates that these foams can still promise considerable reduction in radar cross section with the change of incident angle. Moreover, COMSOL simulation further identifies their good performance in preventing EM interference among different electronic components.

As electromagnetic (EM) pollution intensifies worldwide, developing high-performance EM wave absorbing materials (EWAMs) becomes critical. Researchers from Harbin Institute of Technology, led by Prof. Yunchen Du, have proposed a groundbreaking strategy to fabricate directional 3D macroporous carbon foams decorated with WC1-x nanoparticles via salting-out protein assemblies from egg white. This work pioneers a simple yet scalable route to construct anisotropic carbon-based EWAMs without relying on conventional unidirectional freezing techniques.

Why This Matters

  • Eco-Friendly & Scalable: Utilizes discarded egg white as raw material, avoiding complex and energy-intensive freezing processes.
  • Directional Pore Channels: Enhances impedance matching and EM wave attenuation when waves propagate parallel to the channels.
  • Superior EM Performance: Achieves a minimum reflection loss of −72.0 dB and an effective absorption bandwidth of 6.3 GHz, outperforming most biomass-derived EWAMs.

Innovative Design and Features

  • Salting-Out Self-Assembly: Electrostatic interaction between egg white protein and ammonium metatungstate (AM) drives the formation of vesicles, which assemble into directional flakes after centrifugation.
  • In-Situ WC1-x Formation: During pyrolysis, AM converts into uniformly dispersed WC1-x nanoparticles (<10 nm) on carbon flakes, creating abundant heterogeneous interfaces.
  • Tunable Composition: WC1-x content (21.5–49.9 wt%) is easily controlled by adjusting AM dosage, enabling precise optimization of EM properties.
  • Anisotropic Macropores: Pore size (1–7 μm) and alignment are retained after pyrolysis, facilitating multiple reflections and extending EM wave propagation paths.

Applications and Future Outlook

  • Radar Stealth: CST simulations confirm a 13.6 dB m2 average RCS reduction, demonstrating excellent stealth performance across −90° to 90° incident angles.
  • Chip Anti-Interference: COMSOL modeling shows WCC-2 coating reduces EM leakage from 5.0 to <2.0 V m-1, protecting sensitive electronics.
  • Challenge & Next Step: Current foam size is centimeter-scale; future work will scale up dimensions and refine pore structure control for industrial applications.

This study offers a low-cost, green, and scalable pathway to advanced EWAMs, bridging biomass valorization with next-generation EM protection. Stay tuned for more innovations from Prof. Yunchen Du’s team at HIT!

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Nanoparticles
Physical Sciences > Chemistry > Materials Chemistry > Nanoparticles
Nanoscale Design, Synthesis and Processing
Physical Sciences > Materials Science > Nanotechnology > Nanoscale Design, Synthesis and Processing
Porous Materials
Physical Sciences > Chemistry > Materials Chemistry > Porous Materials
Propagation, transmission, absorption
Physical Sciences > Physics and Astronomy > Optics and Photonics > Classical Optics, Geometric and Wave optics > Propagation, transmission, absorption
  • Nano-Micro Letters Nano-Micro Letters

    Nano-Micro Letters is a peer-reviewed, international, interdisciplinary and open-access journal that focus on science, experiments, engineering, technologies and applications of nano- or microscale structure and system in physics, chemistry, biology, material science, and pharmacy.