As electric vehicles, aerospace and underground instruments demand energy-dense power that survives extreme heat, the cathode–electrolyte interface in solid-state lithium metal batteries (SSLMBs) becomes the weakest link. Now, a National University of Defense Technology team led by Prof. Qingpeng Guo and Prof. Chunman Zheng unveils an ultrathin, ion-electron dual-conductive skin that keeps Ni-rich NCM811 stable even at 100 °C. Their work, published in Nano-Micro Letters, offers a scalable polymerization-cyclization recipe ready for roll-to-roll production.

Why the New Coating Matters
• High-Temperature Resilience: In-cPAN-260@NCM811 retains 86.8 % capacity after 300 cycles at 60 °C and 75 % after 100 cycles at 100 °C—far above the failure point of conventional oxide cathodes.
• Dendrite & Cracking Shield: A 12–15 nm cPAN network coordinates with surface Ni, raising the Ni-migration barrier from 2.83 eV to 3.36 eV and suppressing intergranular fracture under 4.3 V.
• Mixed Conduction: Partially graphitized cPAN delivers 0.14 S cm^-1 electronic and 1.22 × 10^-4 S cm^-1 ionic conductivity, cutting charge-transfer resistance by 40 %.

Innovative Design & Features
• In-situ Polymerization: Acrylonitrile polymerizes directly on NCM811 in LiFSI-containing solvent, ensuring conformal coverage without extra binders.
• Controlled Cyclization: 260 °C air treatment converts 80 % of –CN into C=N/C=C conjugated rings, proven by FTIR, Raman and N 1s XPS.
• PVDF-HFP/LAGP Composite Electrolyte: The 50 µm membrane provides 0.78 mS cm^-1 at 60 °C and stable Li plating for 3000 h.

Applications & Safety Validation
• Pouch-Cell Abuse Tests: LED arrays stay lit after folding, cutting and nail penetration; volume expansion <1 % versus 570 % for liquid cells during 90 °C storage.
• ARC Calorimetry: Self-heating onset rises from 160.9 °C (liquid) to 255.6 °C (solid), with peak runaway temperature dropping 60 %.
• Rate Capability: 163 mAh g^-1 at 0.1 C, 140 mAh g^-1 at 1 C, and only 15.7 mV polarization shift after 50 cycles.

Challenges & Outlook
The team highlights the need for thinner coatings (<5 nm) to push energy density above 400 Wh kg^-1 and for continuous coating lines compatible with dry-electrode calendaring. Future research will couple real-time impedance monitoring with AI-driven cyclization control to extend cycle life beyond 1 000 at 120 °C.

This facile surface-engineering strategy opens a commercially viable route for thermally robust, high-energy SSLMBs in extreme-environment applications.