Multifunctional Asymmetric Bilayer Aerogels for Highly Efficient Electromagnetic Interference Shielding with Ultrahigh Electromagnetic Wave Absorption

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Multifunctional Asymmetric Bilayer Aerogels for Highly Efficient Electromagnetic Interference Shielding with Ultrahigh Electromagnetic Wave Absorption
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Multifunctional Asymmetric Bilayer Aerogels for Highly Efficient Electromagnetic Interference Shielding with Ultrahigh Electromagnetic Wave Absorption - Nano-Micro Letters

Although multifunctional electromagnetic interference (EMI) shielding materials with ultrahigh electromagnetic wave absorption are highly required to solve increasingly serious electromagnetic radiation and pollution and meet multi-scenario applications, EMI shielding materials usually cause a lot of reflection and have a single function. To realize the broadband absorption-dominated EMI shielding via absorption–reflection–reabsorption mechanisms and the interference cancelation effect, multifunctional asymmetric bilayer aerogels are designed by sequential printing of a MXene-graphene oxide (MG) layer with a MG emulsion ink and a conductive MXene layer with a MXene ink and subsequent freeze-drying for generating and solidifying numerous pores in the aerogels. The top MG layer of the asymmetric bilayer aerogel optimizes impedance matching and achieves re-absorption, while the bottom MXene layer enhances the reflection of the incident electromagnetic waves. As a result, the asymmetric bilayer aerogel achieves an average absorption coefficient of 0.95 in the X-band and shows the tunable absorption ability to electromagnetic wave in the ultrawide band from 8.2 to 40 GHz. Finite element simulations substantiate the effectiveness of the asymmetric bilayer aerogel for electromagnetic wave absorption. The multifunctional bilayer aerogels exhibit hydrophobicity, thermal insulation and Joule heating capacities and are efficient in solar-thermal/electric heating, infrared stealth, and clean-up of spilled oil.

As 5G base-stations mushroom and drones patrol from the stratosphere, electromagnetic pollution, infrared surveillance, and oil-spill disasters increasingly arrive in the same breath. In a sweeping review published in Nano-Micro Letters, a Beijing University of Chemical Technology team led by Professors Hao-Bin Zhang and Zhong-Zhen Yu reveals an asymmetric MXene-graphene bilayer aerogel that neutralizes all four threats simultaneously. Printed in minutes from a single emulsion ink, the 12 mg cm-3 foam weighs less than a postage stamp yet delivers >100 dB EMI shielding, 115 °C solar-thermal heating, dynamic IR camouflage, 0.032 W m-1 K-1 thermal insulation, and 10× its own weight in oil absorption—all without external power beyond sunlight or a 1–3.5 V pulse.

Inside the Bilayer Design: From Reflection to Re-Absorption

Traditional metal foils reflect 90 % of incident waves, creating secondary pollution. The new design flips the paradigm:

  • Top MG layer(MXene + GO) fine-tunes impedance like a gateway, letting waves enter instead of bouncing them away.
  • Bottom MXene layer acts as an internal mirror, reflecting any residual energy back through 46 µm spherical closed pores where ohmic loss, dipole polarization, and multiple scattering finish the job.
  • Result: an absorption coefficient of 0.95 across 8.2–40 GHz while reflection stays below 0.05—an order-of-magnitude improvement over copper-backed foams.

Finite-element simulations show electric fields trapped inside the spherical pores rather than the aerogel surface, confirming absorption dominance.

Five Missions, One Material

  1. Electromagnetic Shielding
    3D-printed lattice covers attenuate Bluetooth signals to zero, preserving the >100 dB shielding of copper foil while adding almost no mass.
  2. Solar-Thermal Heating & De-icing
    Under 150 mW cm-2 sunlight, the black MXene surface hits 115 °C in 80 s, melting 0.2 mL of ice in one minute—ideal for aircraft wings or soldier helmets.
  3. Dynamic Infrared Camouflage
    A 1.21 V pulse drives the surface from ambient to 45 °C, matching background heat signatures in real time. Cycle tests over 50 on/off events show <0.5 °C drift.
  4. Thermal Insulation & IR Stealth
    A 1 cm sheet keeps an 80 °C source below 39 °C on the exposed side, cloaking engines from thermal cameras while remaining hand-safe.
  5. Oil-Water Cleanup
    The 131° water-contact-angle surface absorbs cyclohexane in 20 s and viscous crude in 60 s under solar heat, then releases the oil by gentle squeezing—fully reusable after ultrasonic cleaning.

Ink to Infinity—Scalable, Sculptable, Sustainable

The magic starts with a Pickering emulsion ink: MXene and graphene oxide sheets self-assemble with octadecyl amine at the oil-water interface, forming nano-surfactants that jam droplets into a printable gel. Rheology is tuned by stirring speed and phase ratio, enabling direct-ink-writing into lattices, petals, or meter-scale sheets on standard 3-D printers. After freeze-drying, the closed-cell spherical pores survive folding, flexing, and even 3 h of ultrasonic agitation in water.

The entire process uses commodity MXene and GO, no toxic solvents, and is compatible with roll-to-roll molding—clearing the path for kilogram-scale production.

Roadmap to the All-Weather, All-Threat Garment

Next steps embed the aerogel into helmet liners for soldiers, drone skins for logistics, or emergency blankets for disaster zones. Early prototypes already cloak a soldier’s head from IR drones while powering a pocket heater from sunlight alone. One material, five functions, zero compromise—the future of multifunctional protection is ready to print on demand.

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Nanoscale Design, Synthesis and Processing
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Materials for Devices
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  • Nano-Micro Letters Nano-Micro Letters

    Nano-Micro Letters is a peer-reviewed, international, interdisciplinary and open-access journal that focus on science, experiments, engineering, technologies and applications of nano- or microscale structure and system in physics, chemistry, biology, material science, and pharmacy.