Nature‑Inspired Upward Hanging Evaporator with Photothermal 3D Spacer Fabric for Zero‑Liquid‑Discharge Desalination

Nature‑Inspired Upward Hanging Evaporator with Photothermal 3D Spacer Fabric for Zero‑Liquid‑Discharge Desalination
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Nature-Inspired Upward Hanging Evaporator with Photothermal 3D Spacer Fabric for Zero-Liquid-Discharge Desalination - Nano-Micro Letters

While desalination is a key solution for global freshwater scarcity, its implementation faces environmental challenges due to concentrated brine byproducts mainly disposed of via coastal discharge systems. Solar interfacial evaporation offers sustainable management potential, yet inevitable salt nucleation at evaporation interfaces degrades photothermal conversion and operational stability via light scattering and pathway blockage. Inspired by the mangrove leaf, we propose a photothermal 3D polydopamine and polypyrrole polymerized spacer fabric (PPSF)-based upward hanging model evaporation configuration with a reverse water feeding mechanism. This design enables zero-liquid-discharge (ZLD) desalination through phase-separation crystallization. The interconnected porous architecture and the rough surface of the PPSF enable superior water transport, achieving excellent solar-absorbing efficiency of 97.8%. By adjusting the tilt angle (θ), the evaporator separates the evaporation and salt crystallization zones via controlled capillary-driven brine transport, minimizing heat dissipation from brine discharge. At an optimal tilt angle of 52°, the evaporator reaches an evaporation rate of 2.81 kg m−2 h−1 with minimal heat loss (0.366 W) under 1-sun illumination while treating a 7 wt% waste brine solution. Furthermore, it sustains an evaporation rate of 2.71 kg m−2 h−1 over 72 h while ensuring efficient salt recovery. These results highlight a scalable, energy-efficient approach for sustainable ZLD desalination.

As global freshwater demand intensifies, conventional desalination faces mounting challenges from brine disposal and energy consumption. Now, researchers from Donghua University, led by Prof. Haoxuan Li and Prof. Meifang Zhu, have developed a mangrove leaf-inspired upward-hanging evaporator using 3D photothermal spacer fabric (PPSF). This novel design achieves zero-liquid-discharge (ZLD) desalination while maintaining high evaporation rates and enabling simultaneous salt recovery.

Why This Matters

  • Zero Liquid Discharge: Eliminates brine discharge by spatially separating evaporation and crystallization zones.
  • High Efficiency: Achieves 2.81 kg m-2 h-1 evaporation rate with only 0.366 W heat loss under 1-sun illumination.
  • Scalable & Sustainable: Uses low-cost, knit photothermal fabric suitable for large-scale deployment.

Innovative Design

  • Bioinspired Structure: Mimics mangrove transpiration—water rises via capillary action, while salt crystallizes at the lower end.
  • Photothermal Fabric: In situ polymerized polydopamine and polypyrrole on 3D spacer fabric deliver 97.8% solar absorption.
  • Tilt Optimization: A 52° tilt angle minimizes heat loss and maximizes evaporation by suppressing brine flow.

Performance Highlights

  • Stable Operation: Maintains 2.71 kg m-2 h-1 over 72 hours with efficient salt collection (7.28 g over 3 days).
  • Durability: Retains 93% solar absorption and mechanical integrity after 14 days of use.
  • Real-World Validation: Demonstrates 2.8 kg m-2h-1 evaporation under natural sunlight with effective pollutant and salt removal.

This work presents a paradigm shift in solar desalination—integrating biomimetic design, thermal management, and ZLD strategy—for sustainable freshwater and salt co-production.

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Bioinspired Technologies
Technology and Engineering > Biological and Physical Engineering > Biomedical Engineering and Bioengineering > Bioinspired Technologies
Nanoscale Design, Synthesis and Processing
Physical Sciences > Materials Science > Nanotechnology > Nanoscale Design, Synthesis and Processing
Water Treatment
Physical Sciences > Chemistry > Physical Chemistry > Environmental Chemistry > Water Treatment
Environmental Chemistry
Physical Sciences > Earth and Environmental Sciences > Environmental Sciences > Environmental Chemistry
  • Nano-Micro Letters Nano-Micro Letters

    Nano-Micro Letters is a peer-reviewed, international, interdisciplinary and open-access journal that focus on science, experiments, engineering, technologies and applications of nano- or microscale structure and system in physics, chemistry, biology, material science, and pharmacy.