Chemistry in a metallic environment

The most common environment in the solar system is metallic hydrogen, found deep inside Jupiter and Saturn. Little is known of chemistry is these conditions. Using computer simulations, we demonstrate the formation and stability of complex carbon-based hypermolecules in metallic hydrogen.

Published in Astronomy, Chemistry, and Materials

Chemistry in a metallic environment
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Molecules in metallic hydrogen planet
Complex molecules with unusual
compositions form deep in planets

Chemistry usually takes place in aqueous solution, air or vacuum.  Stable chemical compounds are usually limited by the number of valence electrons available for bond formation.  But the most common environment in the solar system is high pressure metallic hydrogen, wherein   extra electrons are available  and charged molecules are also possible.   So we can expect the rules of organic chemistry to be very different. 

In Nature Communications,  Jakkapat Seeyangnok and colleagues report the formation of small molecules in fluid metallic hydrogen.  There are the counterparts of water, methane, ammonia, ethane and methanol, but with extra hydrogen atoms forming H3O, NH4, CH6, CH10, CH4OH.  These compounds are known as hypermolecules, on account of these excess hydrogens.   Analysis using standard chemistry techniques reveals these molecules to be covalently bonded.   The work strongly suggests that unconventional organic chemistry with complex molecules can exist in a fluid metallic hydrogen environment, such as found in brown dwarfs.  Quite how complex these hypermolecules can become remains to be ascertained.

In addition, we found that metallic hydrogen can act as a super-solvent for almost all elements, He and Ne being exceptions.  This relates our study to the surprising discovery by the recent Juno mission that Jupiter appears to have no distinct rocky core:  materials which could form rocks are simply dissolved in the metallic hydrogen.

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Analytical Chemistry
Physical Sciences > Chemistry > Analytical Chemistry
Astronomy, Cosmology and Space Sciences
Physical Sciences > Physics and Astronomy > Astronomy, Cosmology and Space Sciences
Materials Characterization Technique
Physical Sciences > Materials Science > Materials Characterization Technique

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