Behind the Paper
The real stories behind the latest research papers, from conception to publication, the highs and the lows
Catalytic Asymmetric C-Si Bond Activation via Torsional Strain-Promoted Rh-Catalyzed Aryl-Narasaka Acylation
Aryl Narasaka acylation is realized by the catalysis of chiral rhodium complex which is in situ formed of [Rh(CO)2Cl]2 and phosphoramidite ligand. Computational studies show that the storioanl stain is about 12.58 kcal mol-1, which efficiently accelerate the C-Si bond cleavage.
Digital health interventions – how are we going with evidence?
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